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Are you thinking of this?http://fo2238.fodev.net/wiki/PoisonThink it was used to assasinate Councilman Westin in FO2 as a Bishop quest?
This cartridge appears to be ammo for the HN Needler Pistol. Each 'bullet' is a small hypodermic designed to inject a target with its contents upon impact .
Like why would you be poisoned if combat/power/metal armor was not bypassed? It'd need some kind of new rules how poisons work.